Published January 1993 | Version v1
Journal article Metadata-only

Synthesis and crystal structure of (m-carboran-9-yl)(diisopropoxyphosphoryl)mercury

Creators

  • 1. AN SSSR, Moscow (Russian Federation). Inst. Ehlementoorganicheskikh Soedinenij

Description

Carborane derivatives m-C2H2B10H9P(O) · (OPr-iso)2, containing the chain B-Hg-P, was synthesized by means of interaction between bis(m-carbonyl)mercury and [(iso-PrO)2PO]2Hg. The crystals of the compound prepared are monoclinic, at 20 degC a = 11.067(2), b = 14.015(3), c 13.387(3) A, β = 107.78(3), V = 1977,2(7) A3 dcalcd 1.1710 g/cm3, Z = 4, sp. gr. P21/c. The length of B-Hg covalent σ-bond is 2.13 A. Molecules in the crystal are jointed in centrally symmetric associates at the expense of Hg...O coordination bond

Additional details

Additional titles

Original title (Russian)
Синтез и кристаллическая структура (м-карборан-9-ил)(диизопропоксифосфорил)ртути

Publishing Information

Journal Title
Metalloorganicheskaya Khimiya
Journal Volume
6
Journal Issue
1
Journal Page Range
p. 88-92.
ISSN
0235-0114
CODEN
MEKHEX

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
24074124
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
BOND LENGTHS; CARBORANES; CHEMICAL PREPARATION; LATTICE PARAMETERS; MERCURY COMPOUNDS; MONOCLINIC LATTICES; ORGANIC PHOSPHORUS COMPOUNDS; SPACE GROUPS
Descriptors DEC
CRYSTAL LATTICES; CRYSTAL STRUCTURE; ORGANIC BORON COMPOUNDS; ORGANIC COMPOUNDS; SYMMETRY GROUPS; SYNTHESIS