Published February 1978 | Version v1
Journal article

Deuteron magnetic resonance in KD3(SeO3)2

  • 1. Hokkaido Univ., Sapporo (Japan). Research Inst. of Applied Electricity

Description

Quadrupole coupling constant and the direction of the principal axes of EFG tensor of deuterons in KD3(SeO3)2 are obtained from 40 to -1060C. It is confirmed that there exist two symmetrically inequivalent deuterons D(1) and D(2), and D(1) is ordered in the disordered phase. Deuterons D(2) are found to be dynamically disordered in the disordered phase. In the ordered phase, D(1) sites are divided into two inequivalent groups while the number of D(2) sites remains unchanged. The splitting of the resonance line of D(1) in the ordered phase depends on temperature as (T sub(tr)-T)sup(β), where T sub(tr) is 24.90C and β is about 0.52 +- 0.08 in the temperature from 24.4 to 220C and 0.46+-0.01 from 22 to 30C. The relation between the splitting and the order parameter is discussed. (auth.)

Additional details

Identifiers

Publishing Information

Journal Title
Journal of the Physical Society of Japan
Journal Volume
44
Journal Issue
2
Series
J. Phys. Soc. Jpn.
Journal Page Range
537-543
ISSN
0031-9015

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