Published 1987 | Version v1
Book Metadata-only

X-ray structure study of Mn(2) complexes with malonic acid dihydrazide of the type Mn(DM)2X2·nH2O, where X=Cl-, 1/2SO42-, ClO4-, I-; n=0-4

Creators

Description

The crystal and molecular structure as well as stereochemical peculiarities of the Mn(DM)2T2 complex (DM-malonic acid dihydrazide) are investigated by the X-ray structure study. The parameters of a monoclinic cell are: a=19.995(6), b=6.885(1), c=16.946(5) A; β=134.34(1); sp. gr. C2/c, Z=4; dcalcd=2.31 g/cm3. The structure is solved by the method of a heavy ion. It belongs to the number of polymer-ion structures and it is constructed from metal-dihydrazide polymer chains and I- anions

Additional details

Additional titles

Original title (Russian)
Рентгеноструктурное исследование комплексных соединений Мн(2) с дигидразидом малоновой кислоты типа Мн(DM)

Publishing Information

Publisher
Metsniereba.
Imprint Place
Tbilisi (USSR)
Imprint Title
Investigation in chemistry of complexes and compounds of certain transition and rare metals. No. 4
Journal Page Range
p. 3-39.

INIS

Country of Publication
USSR
Country of Input or Organization
USSR
INIS RN
20028781
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
DENSITY; HYDRAZIDES; IODIDES; LATTICE PARAMETERS; MANGANESE COMPLEXES; MOLECULAR STRUCTURE; MONOCLINIC LATTICES; SPACE GROUPS; STEREOCHEMISTRY
Descriptors DEC
COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; HALIDES; HALOGEN COMPOUNDS; IODINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PHYSICAL PROPERTIES; SYMMETRY GROUPS; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
13 refs.; 19 figs.; 23 tabs. Imprint:Issledovaniya v oblasti khimii kompleksnykh i prostykh soedinenij nekotorykh perekhodnykh i redkikh metallov. Vypusk 4.