Published 1975
| Version v1
Journal article
Evidences of ion-cluster formation on the reactions of [I.T.]-activated 80Br in Hsup(80m)Br-CH4 system
Description
The effects of various additives having different dipole moment and the temperature dependence on the reaction of isometric transition-activated 80Br in the Hsup(80m)Br-Ch4 system have been investigated. It was found that the formation of individual organic products, such as CH380Br and CH280BrBr, were significantly affected by adding CO or HCl additive to the system, and that the distributions of these products were influenced by the temperature of the experimental system. These results present direct evidences to support the suggestion that the charge complex, [CH480Br+]*, formed in the primary step forms the ion-cluster with surrounding molecules in the subsequent steps to form the final products. (F.Gy.)
Additional details
Publishing Information
- Journal Title
- Radiochem. Radioanal. Lett.
- Journal Volume
- 20
- Journal Issue
- 4-5
- Series
- Radiochem. Radioanal. Lett.
- Journal Page Range
- 299-305
INIS
- Country of Publication
- Hungary
- Country of Input or Organization
- Hungary
- INIS RN
- 7223236
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ADDITIVES; BROMINE 80; CHEMICAL REACTION KINETICS; HOT ATOM CHEMISTRY; HYDROBROMIC ACID; ION PAIRS; ISOMERIC TRANSITIONS; TEMPERATURE DEPENDENCE; TETRACHLOROMETHANE
- Descriptors DEC
- BETA DECAY RADIOISOTOPES; BETA-MINUS DECAY RADIOISOTOPES; BETA-PLUS DECAY RADIOISOTOPES; BROMINE ISOTOPES; CHEMISTRY; ELECTRON CAPTURE RADIOISOTOPES; ENERGY-LEVEL TRANSITIONS; HOURS LIVING RADIOISOTOPES; HYDROCARBONS; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INTERMEDIATE MASS NUCLEI; INTERNAL CONVERSION RADIOISOTO; ISOTOPES; KINETICS; MINUTES LIVING RADIOISOTOPES; NUCLEI; ODD-ODD NUCLEI; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; RADIOCHEMISTRY; RADIOISOTOPES; REACTION KINETICS
Optional Information
- Notes
- 6 refs.; 2 tabs.