Published March 15, 1978
| Version v1
Journal article
The effect of temperature on the optical spectra and the yields of solvated electrons and ion-pairs in amines
- 1. Atomic Energy of Canada Ltd., Chalk River, Ontario. Chalk River Nuclear Labs.
Description
Optical absorption spectra for the solvated electron, esub(s)-, and ion-pairs, (Na+, esub(s)-), have been observed in methylamine, ethylamine, and isopropylamine, at temperatures ranging from 184 to 338 K. Changes in the (Na+, esub(s)-) spectra, relative to esub(s)-, are consistent with a gradual transition in the ion-pair structure toward a more 'electron-like' entity with decreasing temperature and increasing solvent polarity
Additional details
Identifiers
- DOI
- 10.1139/v78-139;
Publishing Information
- Journal Title
- Canadian Journal of Chemistry
- Journal Volume
- 56
- Journal Issue
- 6
- Series
- Can. J. Chem.
- Journal Page Range
- 839-843
- ISSN
- 0008-4042
INIS
- Country of Publication
- Canada
- Country of Input or Organization
- Canada
- INIS RN
- 9397664
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- ABSORPTION SPECTRA; AMINES; ELECTRON BEAMS; G VALUE; INFRARED SPECTRA; ION PAIRS; LOW TEMPERATURE; MEDIUM TEMPERATURE; METHYLAMINE; PULSED IRRADIATION; RADIATION CHEMISTRY; SODIUM COMPOUNDS; SOLVATED ELECTRONS; TEMPERATURE DEPENDENCE; VISIBLE SPECTRA
- Descriptors DEC
- ALKALI METAL COMPOUNDS; BEAMS; CHEMISTRY; ELECTRONS; ELEMENTARY PARTICLES; FERMIONS; IRRADIATION; LEPTON BEAMS; LEPTONS; ORGANIC COMPOUNDS; PARTICLE BEAMS; SPECTRA
Optional Information
- Notes
- 30 refs.; Updated automatically by Metadata and Full-Text Enrichment Agent