Conceptual development of a building-integrated photovoltaic–radiative cooling system and preliminary performance analysis in Eastern China

Highlights: •A specific spectral characteristic for both PV and RC was proposed. •The PV/RC hybrid system based on spectral characteristic is original. •A thermal model of the system was established and the performance was analyzed. •The performance comparison with the conventional PV system was conducted. •The system shows considerable performance for both PV and RC. -- Abstract: Building-integrated photovoltaic/thermal (BIPV/T) technology has been receiving considerable research attention because of its ability to generate electricity and thermal energy simultaneously. However, space cooling is crucial for buildings in hot regions where space heating is of little use. This study proposed a building-integrated photovoltaic–radiative cooling system (BIPV–RC) that can generate electricity via photovoltaic (PV) conversion during daytime and generate cooling energy via radiative cooling (RC) during nighttime to satisfy the demand in such areas. The selective plate, which is the main component of the BIPV–RC system, exhibits high spectral absorptivity (emissivity) in the PV conversion band of crystalline silicon solar cells and in the atmospheric window band (i.e., 0.3–1.1 μm and 8–13 μm), as well as low spectral absorptivity (emissivity) in other bands. A quasi-steady-state mathematical model was built, and its performance under realistic ambient conditions was analyzed. The electrical efficiencies of the BIPV–RC and conventional BIPV systems were then compared under different solar radiations. Comparison results show that the annual electricity production and cooling energy gain of the BIPV–RC system in Hefei reached 156.74 kW h m⁻² (equivalent to 564.26 MJ m⁻²) and 579.91 MJ m⁻², respectively. The total electricity production and cooling energy gain of this system are 96.96% higher than those of the BIPV system. Parametric studies show that the precipitable water vapor amount has remarkable effects on the nocturnal RC performance of the BIPV–RC system. A small precipitable water vapor amount corresponds to a high nocturnal RC power, thereby implying that a dry climate condition benefits the nocturnal RC of this system.