Published October 2007
| Version v1
Journal article
Interactions of lanthanide atoms: Comparative ab initio study of YbHe, Yb2 and TmHe, TmYb potentials
- 1. Moscow State Univ., Dept. of Chemistry (Russian Federation)
- 2. Warsaw Univ., Faculty of Chemistry (Poland)
- 3. Oakland Univ., Dept. of Chemistry, MI (United States)
Description
The results of high-level ab initio calculations are reported for the interatomic potentials describing YbHe, Yb2, TmHe and TmYb van der Waals interactions. It is found that the interaction properties of Tm and Yb are very similar and the interaction anisotropy in the TmHe and TmYb complexes is very small. We analyze the long-range behavior of the isotropic and anisotropic interaction potentials and discuss some implications for cold and ultracold atomic collisions of the lanthanide atoms. (authors)
Availability note (English)
Available from doi:Additional details
Identifiers
Publishing Information
- Journal Title
- European Physical Journal. D, Atomic, Molecular and Optical Physics
- Journal Volume
- 45
- Journal Issue
- no.1
- Journal Page Range
- p. 147-153
- ISSN
- 1434-6060
INIS
- Country of Publication
- France
- Country of Input or Organization
- France
- INIS RN
- 39031352
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ANISOTROPY; ELECTRONIC STRUCTURE; HELIUM COMPOUNDS; INTERACTION RANGE; INTERATOMIC FORCES; INTERMOLECULAR FORCES; POTENTIALS; THULIUM COMPOUNDS; VAN DER WAALS FORCES; YTTERBIUM COMPOUNDS
- Descriptors DEC
- DISTANCE; RARE EARTH COMPOUNDS; RARE GAS COMPOUNDS
Optional Information
- Notes
- 42 refs.