Published October 2007 | Version v1
Journal article

Interactions of lanthanide atoms: Comparative ab initio study of YbHe, Yb2 and TmHe, TmYb potentials

  • 1. Moscow State Univ., Dept. of Chemistry (Russian Federation)
  • 2. Warsaw Univ., Faculty of Chemistry (Poland)
  • 3. Oakland Univ., Dept. of Chemistry, MI (United States)

Description

The results of high-level ab initio calculations are reported for the interatomic potentials describing YbHe, Yb2, TmHe and TmYb van der Waals interactions. It is found that the interaction properties of Tm and Yb are very similar and the interaction anisotropy in the TmHe and TmYb complexes is very small. We analyze the long-range behavior of the isotropic and anisotropic interaction potentials and discuss some implications for cold and ultracold atomic collisions of the lanthanide atoms. (authors)

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Publishing Information

Journal Title
European Physical Journal. D, Atomic, Molecular and Optical Physics
Journal Volume
45
Journal Issue
no.1
Journal Page Range
p. 147-153
ISSN
1434-6060

Optional Information

Notes
42 refs.