Published September 1985
| Version v1
Journal article
Cationic complexes of ruthenium(II) containing phosphine, carboxylato, and nitrato ligands
- 1. Council for Scientific and Industrial Research, Pretoria (South Africa). National Chemical Research Lab.
Description
Reaction of [(eta-C8H12)RuH(NH2NMe2)3]PF6 with the acids, HX (X = RCOO,NO3), followed by treatment with mono- and bidentate tertiary phosphines provides general, high-yield synthetic routes to complexes of the type [RuXL4]PF6(X = O2CR, R = H, CF3, Ph,L2 = bis(diphenylphosphino)methane, bis(diphenylphosphino)propane, L = PMe2Ph; X = O2NO,L2 = bis(diphenylphosphino)methane, bis(diphenylphosphino)-propane], and [RuH(O2CR)L4] (R = CF3,L2 = bis(diphenylphosphino)ethane, bis(diphenylphosphino)propane]
Additional details
Publishing Information
- Journal Title
- S. Afr. J. Chem.
- Journal Volume
- 38
- Journal Issue
- 3
- Series
- S. Afr. J. Chem.
- Journal Page Range
- 149-150
- ISSN
- 0379-4350
- CODEN
- SAJCD
INIS
- Country of Publication
- South Africa
- Country of Input or Organization
- South Africa
- INIS RN
- 17008612
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- CARBOXYLIC ACIDS; CHEMICAL PREPARATION; COMPILED DATA; HYDROGEN 1; INFRARED SPECTRA; LIGANDS; NITRATES; NITRIC ACID; NMR SPECTRA; PHOSPHINES; PHOSPHORUS 31; RUTHENIUM COMPLEXES
- Descriptors DEC
- COMPLEXES; DATA; HYDROGEN COMPOUNDS; HYDROGEN ISOTOPES; INFORMATION; INORGANIC ACIDS; ISOTOPES; LIGHT NUCLEI; NITROGEN COMPOUNDS; NUCLEI; NUMERICAL DATA; ODD-EVEN NUCLEI; ORGANIC ACIDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; PHOSPHORUS ISOTOPES; SPECTRA; STABLE ISOTOPES; SYNTHESIS; TRANSITION ELEMENT COMPLEXES