Published 1989
| Version v1
Journal article
Infrared study on β-radiolysis in methanol-T2O system
Creators
- 1. Toyama Univ. (Japan). Faculty of Science
- 2. Toyama Univ. (Japan). Tritium Research Center
Description
β-radiolysis in a methanol-T2O system in a gaseous state was studied by means of infrared spectroscopy over a period of 10 months. Slow formation of CH2TOH was found. The main product was CO, with small amounts of CH4, HCO2CH3, CH2 (OCH3)2 and (CH3)2O; ethylene glycol and H2CO were not found. This result, which is quite different from that of γ-radiolysis, is explained in terms of surface reactions on stainless steel. (orig.)
Additional details
Publishing Information
- Journal Title
- Radiochimica Acta
- Journal Volume
- 46
- Journal Issue
- 4
- Series
- Radiochim. Acta.
- Journal Page Range
- 205-208
- ISSN
- 0033-8230
- CODEN
- RAACA
INIS
- Country of Publication
- Germany
- Country of Input or Organization
- Germany
- INIS RN
- 20055391
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Descriptors DEI
- BETA DECAY; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; COMPARATIVE EVALUATIONS; G VALUE; GAMMA RADIATION; GASES; INFRARED SPECTRA; METHANOL; MIXTURES; RADIOLYSIS; TRITIUM OXIDES; WALL EFFECTS
- Descriptors DEC
- ALCOHOLS; CHEMICAL RADIATION EFFECTS; CHEMICAL REACTIONS; DECAY; DECOMPOSITION; DISPERSIONS; ELECTROMAGNETIC RADIATION; EVALUATION; FLUIDS; HYDROGEN COMPOUNDS; HYDROXY COMPOUNDS; IONIZING RADIATIONS; KINETICS; NUCLEAR DECAY; ORGANIC COMPOUNDS; RADIATION EFFECTS; RADIATIONS; REACTION KINETICS; SPECTRA; TRITIUM COMPOUNDS