The unexpected absence of Kondo resonance in the photoemission spectrum of CeAl2

We study the temperature dependent Ce 4f spectral evolution of a well known Kondo system, CeAl2, for a range extending beyond 2 eV below the Fermi level, using photoemission spectroscopy. Interestingly, the spectral evolution is inconsistent with the predictions of the many-body spectral function calculations corresponding to the Kondo resonance interpretation of the screened Ce 4f photoemission features. In order to explain our spectral evolution we propose the phenomenon of collapse of the Kondo singlet wavefunction upon photoelectron kinetic energy measurement. Our proposal suggests that the screened final states in photoemission spectroscopy are not quantum states. (fast track communication)