Published September 1980
| Version v1
Journal article
Asymptotic behavior of the ground-state-energy expansion for H2+ in terms of internuclear separation
Creators
- 1. Quantum Theory Group, Department of Applied Mathematics, University of Waterloo, Waterloo, Ontario N2L 3G1,, Canada
Description
The asymptotic behavior of the coefficients a/sub n/ in the expansion of the ground-state energy of the hydrogen molecular ion in terms of the inverse powers of the internuclear separation is found to be a/sub n/=-(n+1)exclamation2/sup -n/e-2[1+2n-1-20n-2-45n-3 +O(n-4)]. The first two terms of this numerically obtained expression agree with the ''asymptotic conjecture'' involving the lowest excitation energy of H2+
Additional details
Publishing Information
- Journal Title
- Phys. Rev., A
- Journal Volume
- 22
- Journal Issue
- 3
- Series
- Phys. Rev., A.
- Journal Page Range
- 793-796
- ISSN
- 0556-2791
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 11566661
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ASYMPTOTIC SOLUTIONS; GROUND STATES; HYDROGEN IONS 2 PLUS; INTERATOMIC DISTANCES; POTENTIAL ENERGY; SERIES EXPANSION
- Descriptors DEC
- CATIONS; CHARGED PARTICLES; DISTANCE; ENERGY; ENERGY LEVELS; HYDROGEN IONS; IONS; MOLECULAR IONS