Published January 1995
| Version v1
Journal article
Electrocrystallization of UO2±X from K2MoO4-K2Mo2O7-UO2MoO4 molten salt
Description
The behavior of uranyl ions in molten potassium polymolybdates at 1073-1173 K in air is studied by voltammetry and chronopotentiometry. An exchange reaction occurs between the electrolysis products, i.e., UO2±X and MoO2-y, in which MoO2 acts as an O2- acceptor. The conditions are found that enable the O/U ratio in UO2±X to be controlled from 1.981 to 2.105 by electrolysis of polymolybdate melts
Additional details
Publishing Information
- Journal Title
- Radiochemistry (New York)
- Journal Volume
- 36
- Journal Issue
- 3
- Journal Page Range
- p. 257-261.
- ISSN
- 1066-3622
- CODEN
- RDIOEO
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 26049378
- Subject category
- S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
- Resource subtype / Literary indicator
- Translation
- Descriptors DEI
- CHEMICAL PREPARATION; CRYSTALLIZATION; MOLTEN SALTS; MOLYBDATES; POTENTIOMETRY; STOICHIOMETRY; URANIUM OXIDES; VOLTAMETRY
- Descriptors DEC
- ACTINIDE COMPOUNDS; CHALCOGENIDES; MOLYBDENUM COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PHASE TRANSFORMATIONS; SALTS; SYNTHESIS; TITRATION; TRANSITION ELEMENT COMPOUNDS; URANIUM COMPOUNDS
Optional Information
- Notes
- Translated from Radiokhimiya; 36: No. 3, 233-236(May-Jun 1994).