Published August 1978
| Version v1
Journal article
Formation of nitrogen complexes when [Ru(NH3)5H2O]2+ ion reaction with diazo-acetic ester and aromatic salts of diazonium
Creators
- 1. AN SSSR, Moscow. Inst. Ehlementoorganicheskikh Soedinenij
Description
A possibility of formation of nitrogen complexes during transition metal compound interaction with aliphatic and aromatic diazo compounds is studied. It is shown that at the interaction of [Ru(NH3)5H2O]2+ with diazo-acetic ester in water (pH7) at 20 deg, quick splitting of the CN-bond in the ester molecule takes place with the formation of [Ru(NH3)5N2]2+ and [(NH3)5RuN2Ru(NH3)5]4+ (NRRN) nitrogen complexes. The sum yield of complexes comprises 86% taking into acount diazo-acetic ester. Aromatic salts of diazonium, n-O3SC6H4N2 and p-quinone diazide react with the [Ru(NH3)5H2O]2+ excess forming NRRN (the yield equals 40-53%). The reaction mechanism is discussed
Additional details
Additional titles
- Original title (Russian)
- Образование азотных комплексов при взаимодействии иона [Ру(NH
Publishing Information
- Journal Title
- Koord. Khim.
- Journal Volume
- 4
- Journal Issue
- 8
- Series
- Koord. Khim.
- Journal Page Range
- 1248-1255
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 10444127
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AMMONIA; AQUEOUS SOLUTIONS; CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; DIAZO COMPOUNDS; RUTHENIUM COMPLEXES
- Descriptors DEC
- COMPLEXES; DISPERSIONS; HOMOGENEOUS MIXTURES; HYDRIDES; HYDROGEN COMPOUNDS; KINETICS; MIXTURES; NITROGEN COMPOUNDS; NITROGEN HYDRIDES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; REACTION KINETICS; SOLUTIONS; SYNTHESIS; TRANSITION ELEMENT COMPLEXES