Effect of pH on enhancement of hydrogen storage capacity in carbon nanotubes on a copper substrate
- 1. Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan 87317 (Iran, Islamic Republic of)
- 2. Faculty of Physics, University of Kashan, Kashan 87317 (Iran, Islamic Republic of)
- 3. Department of Analytical Chemistry, Faculty of Chemistry, University of Kashan, Kashan 87317 (Iran, Islamic Republic of)
Description
Electrochemical storage of hydrogen in Cu–CNTs (copper and carbon nanotubes) electrodes was studied by Chronopotentiometry technique. In this project effective absorption factors in atomic hydrogenation by CNTs such as charge/discharge (C&D) cyclic number, current and also different pHs were studied. Acidic method was used for purifying and functionalizing the CNTs, and the outputs were characterized using XRD spectroscopy. The CNTs were deposited on copper foam with nano metric porosity by electrophoretic method (EPD). By comparing the results of different experiments in different charge and discharge cycles, it was observed that multi-wall carbon nanotubes in the current of 3 mA with pH=5.4 have a maximum discharge capacity about 10,000 mA h/g.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.physb.2017.05.053Additional details
Identifiers
- DOI
- 10.1016/j.physb.2017.05.053;
- PII
- S0921-4526(17)30286-7;
Publishing Information
- Journal Title
- Physica. B, Condensed Matter
- Journal Volume
- 526
- Journal Page Range
- p. 143-148
- ISSN
- 0921-4526
- CODEN
- PHYBE3
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 49106555
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- CARBON NANOTUBES; COPPER; ELECTROCHEMISTRY; ELECTROPHORESIS; FOAMS; HYDROGEN STORAGE; HYDROGENATION; PH VALUE; X-RAY DIFFRACTION
- Descriptors DEC
- CARBON; CHEMICAL REACTIONS; CHEMISTRY; COHERENT SCATTERING; COLLOIDS; DIFFRACTION; DISPERSIONS; ELEMENTS; METALS; NANOSTRUCTURES; NANOTUBES; NONMETALS; SCATTERING; STORAGE; TRANSITION ELEMENTS
Optional Information
- Copyright
- Copyright (c) 2017 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.