Published January 10, 1987 | Version v1
Journal article Metadata-only

Reaction of trialkylstannylacetylenes with perfluoroiodoalkanes

Creators

  • 1. Lensovet Leningrad Technological Institute (USSR)

Description

It is known that upon heating or UV irradiation perfluoroiodoalkanes R/sub F/I split hexaalkyldistannanes R3SnSnR3, giving trialkylstannyl iodides and trialkylperfluoroalklstannanes R/sub F/SnR3. The authors showed with reference to trimethylstannylphenylacetylenes that upon IV irradiation perfluoroiodoalkanes react with trialkylstannylacetylenes to give primarily perfluoroalkylacetylenes. Yields of target products reach 50%

Additional details

Publishing Information

Journal Title
J. Gen. Chem. USSR (Engl. Transl.)
Journal Volume
56
Journal Issue
7
Series
J. Gen. Chem. USSR (Engl. Transl.).
Journal Page Range
1474-1475
ISSN
0022-1279
CODEN
JGCHA

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
19061988
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; S74: ATOMIC AND MOLECULAR PHYSICS;
Resource subtype / Literary indicator
Translation
Descriptors DEI
ALKYNES; CHEMICAL REACTION YIELD; CHEMICAL SHIFT; COUPLING CONSTANTS; FLUORINE 19; J-J COUPLING; NMR SPECTRA; ORGANIC FLUORINE COMPOUNDS; ORGANIC IODINE COMPOUNDS; PHOTOCHEMISTRY; TIN COMPLEXES; ULTRAVIOLET RADIATION
Descriptors DEC
CHEMISTRY; COMPLEXES; COUPLING; ELECTROMAGNETIC RADIATION; FLUORINE ISOTOPES; HYDROCARBONS; INTERMEDIATE COUPLING; ISOTOPES; LIGHT NUCLEI; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; RADIATIONS; SPECTRA; STABLE ISOTOPES

Optional Information

Notes
Translated from Zh. Obshch. Khim.; 56: No. 7, 1663(Jul 1986).