Published November 1981
| Version v1
Journal article
The system CsF+CaCl2 reversible CsCl+CaF2
Creators
- 1. Rostovskij-na-Donu Inzhenerno-Stroitel'nyj Inst. (USSR)
Description
The meltability diagram of the ternary mutual system Cs, Ca parallel F, Cl is studied using the visual-polythermal and partially differential thermal methods of analysis. Seven crystallization fields, which belong to components and compounds, are observed. The melting temperatures of four non-variant compositions are found. The thermodynamic analysis of the exchange reactions of the systems formed with fluorides and chlorides of alkali metals and calcium, i.e. M1, Ca parallel F, Cl (M1 - Li, Na, K, Rb, Cs) is carried out. The values of thermodynamic functions (ΔH and ΔG) of the exchange reactions of the M1, Ca parallel F, Cl systems are presented for 298, 500 and 1000 K
Additional details
Additional titles
- Original title (Russian)
- Система CsF+CaCl
Publishing Information
- Journal Title
- Zh. Neorg. Khim.
- Journal Volume
- 26
- Journal Issue
- 11
- Series
- Zh. Neorg. Khim.
- Journal Page Range
- 3094-3097
- ISSN
- 0044-457X
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 13674282
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CALCIUM CHLORIDES; CALCIUM FLUORIDES; CESIUM CHLORIDES; CESIUM FLUORIDES; CHEMICAL REACTIONS; ENTHALPY; EUTECTICS; FORMATION FREE ENTHALPY; HIGH TEMPERATURE; MEDIUM TEMPERATURE; MELTING POINTS; PHASE DIAGRAMS
- Descriptors DEC
- ALKALI METAL COMPOUNDS; ALKALINE EARTH METAL COMPOUNDS; CALCIUM COMPOUNDS; CESIUM COMPOUNDS; CHLORIDES; CHLORINE COMPOUNDS; DIAGRAMS; ENERGY; FLUORIDES; FLUORINE COMPOUNDS; FREE ENTHALPY; HALIDES; HALOGEN COMPOUNDS; INFORMATION; PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES; TRANSITION TEMPERATURE
Optional Information
- Notes
- For English translation see the journal Russian Journal of Inorganic Chemistry (UK).