Published January 1995 | Version v1
Journal article

Studies on azide complexes of neodymium(III)- part XII

  • 1. Kuwait Univ., Kuwait (Kuwait). Dept. of Chemistry

Description

The spectrophotometric measurements carried out in aqueous solutions containing Nd3+ and N3- ions, show the formation of a weak Nd(N3)2+ complex ion in 1:1 molar ratio. The stability constant of the complex has been measured at 25 ± 1 degC, pH=5.0 and at an ionic strength=2.0 M (NaClO4), using both Scott and dilution methods and the values are found to be (50.1 ± 0.5) x 10-2 and (49.9 ± 1.6) x 10-2 respectively. The molar absorptivity values of the complex are (33.24 ± 0.31) and (36.3 ± 0.6) at 575 nm. (author). 11 refs., 2 figs

Additional details

Publishing Information

Journal Title
Indian Journal of Chemistry. Section A: Inorganic, Physical, Theoretical and Analytical
Journal Volume
34
Journal Issue
1
Journal Page Range
p. 70-71.
ISSN
0376-4710
CODEN
IJCADU

INIS

Country of Publication
India
Country of Input or Organization
India
INIS RN
27018688
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION; NEODYMIUM COMPLEXES; SPECTROPHOTOMETRY; STABILITY; STRUCTURAL CHEMICAL ANALYSIS
Descriptors DEC
COMPLEXES; RARE EARTH COMPLEXES; SORPTION