Published 1987
| Version v1
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Regularities of thermochemical characteristics of 1-1, 2-1, 3-1 electrolyte solutions in dimethyl sulfoxide-water and propylene carbonate water mixtures
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Description
In an air-tight tilting calorimeter with an isothermal casing enthalpies of praseodymium chloride solution in water, dimethyl sulfoxide (DMSO) - water mixtures, contaning 3.86 and 18.53 mol.% DMSO, and propylene carbonate (PC) - water mixtures, containing 1.85 and 3.23 mol.% PC are measured. The enthalpies of praseodymium chloride solution in the given mixtures in case of infinite solution dilution are determined. Solvation enthalpies of praseodymium and neodymium chlorides, as well as alkali earth metal and magnesium chlorides in water and DMSO - water and PC - water mixtures are calculated. Regularities in thermochemical characteristics of solutions of the given salts in DMSO - water and PC - water mixtures are discussed
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20059246.pdf
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Additional details
Additional titles
- Original title (Russian)
- Закономерности в термохимических характеристиках растворов 1-1, 2-1, 3-1 электролитов в смесях диметилсульфоксид-вода и пропиленкарбонат-вода
- Augmented title (English)
- 1-1, 2-1, 3-1 electrolytes-electrolytes of idfferent-valent
Publishing Information
- Imprint Title
- Thermodynamics and thermochemistry of solutions
- Journal Page Range
- p. 3-12.
- Report number
- INIS-SU--101
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 20059246
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ALKALINE EARTH METAL COMPOUNDS; AQUEOUS SOLUTIONS; DMSO; HETEROCYCLIC COMPOUNDS; MEDIUM TEMPERATURE; NEODYMIUM CHLORIDES; ORGANIC OXYGEN COMPOUNDS; PRASEODYMIUM CHLORIDES; QUANTITY RATIO; REACTION HEAT; SOLUTION HEAT; SOLVATION
- Descriptors DEC
- CHLORIDES; CHLORINE COMPOUNDS; DISPERSIONS; ENTHALPY; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; MIXTURES; NEODYMIUM COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC SULFUR COMPOUNDS; PHYSICAL PROPERTIES; PRASEODYMIUM COMPOUNDS; RARE EARTH COMPOUNDS; SOLUTIONS; SULFOXIDES; THERMODYNAMIC PROPERTIES
Optional Information
- Notes
- Imprint:Termodinamika i termokhimiya rastvorov.;Trudy instituta. Vypusk 148.