Published May 1999 | Version v1
Journal article Metadata-only

Dependence of unified activity coefficients of ferrocenium iodide in aqueous and mixed water-isopropanol solvents on the nature of salt background

Creators

  • 1. Krasnoyarskaya Gosudarstvennaya Tekhnologicheskaya Akademiya, Krasnoyarsk (Russian Federation)

Description

Unified activity coefficients (y±) of ferrocenium iodide in aqueous and water-isopropanol solvents of different salt composition have been determined by potentiometric method at 298.2 K. Dependence of y± on the nature of cations (Li+, Na+, K+) and anions (Cl-, Br-, I-, CIO4-) in the salt background and their concentration, as well as on the content of isopropanol in mixed solvent, has been studied. Assumption on ferrocenium cation association with iodide- and perchlorate-ions is made. The association constants have been calculated using different standard states

Abstract (Russian)

Потенциометрическим методом при 298.2 К определены единые коэффициенты активности (y±) иодида ферроцения в водных и водно-изопропанольных растворителях различного солевого состава. Изучена зависимость y± от природы катионов (Li+, Na+, K+) и анионов (Cl-, Br-, I-, CIO4-) солевого фона и их концентрации, а также от содержания изопропанола в смешанном растворителе. Сделано предположение об ассоциации катиона ферроцения с иодид- и с перхлорат-ионами. Константы ассоциации рассчитаны с использованием различных стандартных состояний

Additional details

Additional titles

Original title (Russian)
Зависимост' единых коеффициентов активности иодида ферроцения в водных и в смешанных водно-изопропанольных расворителях от природы солевого фона

Publishing Information

Journal Title
Zhurnal Obshchej Khimii
Journal Volume
69
Journal Issue
5
Journal Page Range
p. 762-766
ISSN
0044-460X
CODEN
ZOKHA4

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
31036979
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ALKALI METAL COMPOUNDS; AQUEOUS SOLUTIONS; CHEMICAL REACTIONS; CONCENTRATION RATIO; FERROCENE; HALIDES; IODIDES; MIXED SOLVENTS; PERCHLORATES; PROPANOLS; SALTS; TEMPERATURE RANGE 0273-0400 K; THERMODYNAMIC ACTIVITY
Descriptors DEC
ALCOHOLS; CHLORINE COMPOUNDS; COMPLEXES; DIENES; DISPERSIONS; HALIDES; HALOGEN COMPOUNDS; HYDROCARBONS; HYDROXY COMPOUNDS; IODINE COMPOUNDS; IRON COMPLEXES; MIXTURES; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; POLYENES; SOLUTIONS; SOLVENTS; TEMPERATURE RANGE; TRANSITION ELEMENT COMPLEXES

Optional Information

Notes
24 refs., 1 tab.