An evaluation on the intra-day dynamics, seasonal variations and removal of selected pharmaceuticals and personal care products from urban wastewater treatment plants

Highlights: • Twelve selected PPCPs were frequently detected in two full-scale WWTPs. • Intra-day dynamics of PPCPs suggested the influence of different use patterns. • Some PPCPs in the sewage were temperature dependent while the others were not. • Removal efficiency for the selected PPCPs ranged from 62.5% to 99.7%. • PPCPs concentrations in the influent were influenced by its service population. Pharmaceuticals and personal care products (PPCPs) in wastewater have become an emerging issue due to their negative effects on human health and aquatic ecosystems. Two full-scale municipal and industrial wastewater treatment plants (WWTPs) along the Songhua River were chosen to evaluate the intra-day dynamics, seasonal variations and removal of 12 selected PPCPs. Our results suggested that the selected PPCPs were frequently detected in the influent and effluent. Caffeine was the predominant compound in the influent; while the selected PPCPs was dominated by TCS in the effluent, suggesting the different fates of selected PPCPs in the WWTPs. The intra-day dynamics of PPCPs in the influent were evaluated, suggesting that the 12 PPCPs can be grouped into three categories because of their different use patterns. The analysis of seasonal changes of PPCPs concentrations in the WWTPs suggested that the concentrations of some PPCPs were influenced by the chemical usage, degradation and temperature. The removal efficiency for the PPCPs were very high with the values ranged from 70.0% to 99.7% for WWTP#1, and from 62.5% to 99.4% for WWTP#2. Significant seasonal variations of PPCPs removal efficiency were observed. Base on the mass loading of PPCPs in the two WWTPs, our results suggested that WWTP#1 in the urban core received much more PPCPs in comparison to WWTP#2 in the suburban regions, suggesting that influences of the service population.