Published March 15, 1980
| Version v1
Journal article
Structure of tetrakis(4,4,4-trifluoro-1-phenyl-1,3-butanedionato)uranium
Creators
- 1. Faculte de Pharmacie, 92 Chatenay-Malabry, France
- 2. CEA Centre d'Etudes Nucleaires de Saclay, 91 - Gif-sur-Yvette (France). Service de Chimie-Physique
Description
[U(C10H6F3O2)4], C40H24F12O8U, tetragonal, I41/a, a = 17.70 (2), c = 12.67 (4) A, Z = 4, Msub(r) = 1098, V = 3969 (17) A3. The uranium atom lies on an inversion tetrad axis and is surrounded by eight oxygen atoms forming a double-tetrahedral arrangement. The two U-O distances are 2.326 (7) and 2.355 (8) A. The overall packing is such as to allow van der Waals bonds between F atoms from CF3 groups along the 41 axis. (Auth.)
Additional details
Publishing Information
- Journal Title
- Acta Crystallogr., Sect. B
- Journal Volume
- 36
- Journal Issue
- 3
- Series
- Acta Crystallogr., Sect. B.
- Journal Page Range
- 696-697
- ISSN
- 0567-7408
INIS
- Country of Publication
- Denmark
- Country of Input or Organization
- Denmark
- INIS RN
- 11530616
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- BOND ANGLE; BOND LENGTHS; EXPERIMENTAL DATA; ISOLATED VALUES; KETONES; LATTICE PARAMETERS; ORGANIC FLUORINE COMPOUNDS; TABLES; TETRAGONAL LATTICES; URANIUM COMPLEXES
- Descriptors DEC
- ACTINIDE COMPLEXES; COMPLEXES; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DATA; DATA FORMS; INFORMATION; NUMERICAL DATA; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS