Published 1993
| Version v1
Journal article
Preparation and reactivity of metal-containing monomers. 33. Investigation of the cluster monomer [Fe3O(OCOCH=CH2)6]OH and its polymerization by means of IR, XR, Moessbauer and mass-spectroscopy methods
Creators
- 1. AN SSSR, Chernogolovka (Russian Federation). Otdelenie Inst. Khimicheskoj Fiziki
Description
On the interaction of acrylic acid with freshly prepared iron hydroxide a new cluster monomer, [Fe3O(OCOCH=CH2)6]OH · 3H2O, was synthesized. The monomer was characterized by various physico-chemical methods. It was established that the acid residues are bound to metal atoms via the bridge-like or bidentant carboxy groups, and that the double bonds do not take part in the coordination. The mechanism of thermal fragmentation of [Fe3O(OCOCH=CH2)6]+ cluster has been studied. It has been demonstrated that the radical polymerization of the cluster monomer occurs through a bidentant acrylate groups. The reduction of Fe3+ in the course f polymerization was not obderved
Additional details
Additional titles
- Original title (Russian)
- Poluchenie i reaktsionnaya sposobnost' metallsoderzhashchikh monomerov. Soobshchenie 33. Izuchenie metodami infrakrasnoj, rentgenoflyuorestsentnoj, gamma-rezonansnoj i mass-spektroskopii klasternogo monomera [Fe
Publishing Information
- Journal Title
- Izvestiya Akademii Nauk. Seriya Khimicheskaya
- Journal Issue
- no.10
- Journal Page Range
- p. 1739-1743.
- CODEN
- IASKEA
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 26023648
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACRYLATES; CHEMICAL REACTION KINETICS; IRON COMPOUNDS; MASS SPECTROSCOPY; MOESSBAUER EFFECT; MOLECULAR STRUCTURE; POLYMERIZATION; QUALITATIVE CHEMICAL ANALYSIS; VINYL MONOMERS
- Descriptors DEC
- CARBOXYLIC ACID SALTS; CHEMICAL ANALYSIS; CHEMICAL REACTIONS; KINETICS; MONOMERS; REACTION KINETICS; SPECTROSCOPY; TRANSITION ELEMENT COMPOUNDS