Published July 2008
| Version v1
Journal article
Synthesis of bismuth complexes from bismuth iodide and ammonium and phosphonium salts
- 1. Blagoveshchenskij Gosudarstvennyj Pedagogicheskij Univ., Blagoveshchensk (Russian Federation)
Description
The complexes [Et2NH2]3+[BiCl6]3-, [NH4]+[BiI4(C5H5N)2]-·2C5H5N, [Ph3MeP]2+[BiI5]2-, [Ph3MeP]2+[BiI5(C5H5N)]2-·C5H5N, [Ph3MeP]3+[Bi3I12]3-, [Ph3(i-Pr)P]3+[Bi3I12]3-·2Me2C=O, [Ph3BuP]2+[Bi2I8·2Me2C=O]2-, and [Ph3BuP]2+[Bi2I8·2Me2S=O]2- were obtained by reactions of bismuth iodide with ammonium and phosphonium iodides in acetone (Me2C=O), pyridine (C5H5N), or dimethyl sulfoxide (Me2S=O). The complexes have been characterized by their melting points, IR spectra, and elemental analysis. The structural parameters (bond lengths and bond angles) of the complexes have been evaluated from preliminary X-ray diffraction studies
Abstract (Russian)
Взаимодействием иодида висмута с иодидами аммония и фосфония в ацетоне (Me2C=O), пиридине (C5H5N) или диметилсульфоксиде (Me2S=O) получены комплексы [Et2NH2]3+[BiCl6]3-, [NH4]+[BiI4(С5Н5N)2]-·2C5H5N, [Ph3MeP]2+[BiI5]2-, [Ph3MeP]2+[BiI5(C5H5N)]2-·C5H5N, [Ph3MeP]3+[Bi3I12]3-, [Ph3(i-Pr)P]3+[Bi3I12]3-·2Me2C=O, [Ph3BuP]2+[Bi2I8·2Me2C=O]2-, [Ph3BuP]2+[Bi2I8·2Me2S=O]2-. Комплексы охарактеризованы данными элементного анализа, ИК-спектроскопии и по температурам плавления. На основе предварительных результатов рентгенографических исследований оценены их структурные характеристики (длины и углы химических связей)Additional details
Additional titles
- Original title (Russian)
- Синтез комплексных соединений висмута из иодида висмута и солей аммония, фосфония
Publishing Information
- Journal Title
- Zhurnal Obshchej Khimii
- Journal Volume
- 78
- Journal Issue
- 7
- Journal Page Range
- p. 1089-1092
- ISSN
- 0044-460X
- CODEN
- ZOKHA4
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 40088786
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ACETONE; AMMONIUM COMPOUNDS; BISMUTH COMPLEXES; BOND ANGLE; BOND LENGTHS; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; CHEMICAL REACTION YIELD; DMSO; INFRARED SPECTRA; IODIDES; MELTING POINTS; MOLECULAR STRUCTURE; ORGANIC PHOSPHORUS COMPOUNDS; PYRIDINE
- Descriptors DEC
- AZINES; COMPLEXES; DIMENSIONS; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; IODINE COMPOUNDS; KETONES; LENGTH; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC SULFUR COMPOUNDS; PHYSICAL PROPERTIES; PYRIDINES; SPECTRA; SULFOXIDES; SYNTHESIS; THERMODYNAMIC PROPERTIES; TRANSITION TEMPERATURE; YIELDS
Optional Information
- Notes
- 2 refs.