Published October 31, 2008 | Version v1
Journal article

Photocatalytic transformations of organic sulfur compounds and H2S

  • 1. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk (Russian Federation)

Description

Modern views on the products, pathways and kinetic features of liquid- and gas-phase photocatalytic reactions of sulfur compounds in the presence of heterogeneous and homogeneous photocatalysts are generalised. Attention is focussed on the aliphatic and aromatic reduced sulfur compounds and pesticides. The reaction rate in the liquid and gas phases are analysed as function of solution pH, temperature, catalyst content, substrate concentration, solvent type, air moisture and added oxidants. Photocatalyst deactivation and the ways for recovery of its activity are considered.

Availability note (English)

Available from http://dx.doi.org/10.1070/RC2008v077n10ABEH003805

Additional details

Publishing Information

Journal Title
Russian Chemical Reviews (Print)
Journal Volume
77
Journal Issue
10
Journal Page Range
p. 909-926
ISSN
0036-021X

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
41013525
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
AROMATICS; CATALYSTS; DEACTIVATION; HYDROGEN SULFIDES; ORGANIC SULFUR COMPOUNDS; OXIDIZERS; PESTICIDES; PH VALUE; PHOTOCATALYSIS; REACTION KINETICS; SOLVENTS
Descriptors DEC
CATALYSIS; CHALCOGENIDES; HYDROGEN COMPOUNDS; KINETICS; ORGANIC COMPOUNDS; SULFIDES; SULFUR COMPOUNDS