Published June 1, 2010 | Version v1
Journal article Metadata-only

Nickel-catalyzed reactions of enone with ethylene

Creators

  • 1. Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871 (Japan)

Description

The reaction of (E)-1-phenylbut-2-en-1-one with ethylene in the presence of a catalytic amount of Ni(cod)2 and PCy3 at room temperature gave two kinds of three-component addition products; one is 1,6-enone composed of an enone and two ethylene molecules, and the other is 1,5-diketone composed of two enones and an ethylene. The reactions might proceed via oxidative cyclization of an enone and an ethylene with nickel(0).

Availability note (English)

Available from http://dx.doi.org/10.1088/1742-6596/232/1/012012

Additional details

Identifiers

DOI
10.1088/1742-6596/232/1/012012;

Publishing Information

Journal Title
Journal of Physics. Conference Series (Online)
Journal Volume
232
Journal Issue
1
Journal Page Range
[4 p.]
ISSN
1742-6596

Conference

Title
4. international symposium on atomic technology
Dates
18-19 Nov 2009
Place
Kobe (Japan)

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
42047130
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Resource subtype / Literary indicator
Conference
Descriptors DEI
CATALYSTS; CYCLIZATION; ETHYLENE; KETONES; MOLECULES; NICKEL; OXIDATION; TEMPERATURE RANGE 0273-0400 K
Descriptors DEC
ALKENES; CHEMICAL REACTIONS; ELEMENTS; HYDROCARBONS; METALS; ORGANIC COMPOUNDS; TEMPERATURE RANGE; TRANSITION ELEMENTS