Published July 23, 2007 | Version v1
Report

THERMAL AND SPECTROSCOPIC ANALYSES OF CAUSTIC SIDE SOLVENT EXTRACTION SOLVENT CONTACTED WITH 1 MOLAR AND 3 MOLAR NITRIC ACID

Description

Thermal and spectroscopic analyses were performed on multiple layers formed from contacting Caustic Side Solvent Extraction (CSSX) solvent with 1 M or 3 M nitric acid. A slow chemical reaction occurs (i.e., over several weeks) between the solvent and 1 M or 3 M nitric acid as evidenced by color changes and the detection of nitro groups in the infrared spectrum of the aged samples. Thermal analysis revealed that decomposition of the resulting mixture does not meet the definition of explosive or deflagrating material

Availability note (English)

Available from http://sti.srs.gov/fulltext/WSRC-STI-2007-00385.pdf; PURL: https://www.osti.gov/servlets/purl/914556-jRqelw/

Additional details

Publishing Information

Imprint Pagination
vp.
Report number
WSRC-STI--2007-00385

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
39075472
Subject category
S11: NUCLEAR FUEL CYCLE AND FUEL MATERIALS;
Resource subtype / Literary indicator
Non-conventional Literature
Descriptors DEI
CHEMICAL REACTIONS; NITRIC ACID; ORGANIC SOLVENTS; SAVANNAH RIVER PLANT; SOLVENT EXTRACTION; SPECTROSCOPY; THERMAL ANALYSIS
Descriptors DEC
EXTRACTION; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; NATIONAL ORGANIZATIONS; NITROGEN COMPOUNDS; NONAQUEOUS SOLVENTS; OXYGEN COMPOUNDS; SEPARATION PROCESSES; SOLVENTS; US AEC; US DOE; US ERDA; US ORGANIZATIONS

Optional Information

Contract/Grant/Project number
AC09-96SR18500
Notes
doi 10.2172/914556
Funding organization
US Department of Energy (United States)