Published February 2003
| Version v1
Journal article
Metal-metal interaction in binuclear ferrocene-arene complexes
- 1. Hiroshima Univ. (Japan). Radioisotope Center
- 2. Hiroshima Univ. (Japan). Graduate School of Science
- 3. Tokyo Metropolitan Univ., Hachioji (Japan). Graduate School of Science
Description
Electronic interaction between two iron atoms was studied in the ferrocene-arene binuclear complexes ([Fc(CH2)nPhFeCp]+PF6-) by using 57Fe Moessbauer spectroscopy and cyclic voltammetry(CV). By comparing the CV data between Fc(CH2)nPh and its arene complexes it was revealed that the considerable electronic interaction between two iron atoms exists in the n 0 complex and a slight interaction in the n = 1 complex, while no significant interaction exists in n = 2, 3, 4, and 6 complexes. These results were discussed by using MO calculations. (author)
Additional details
Publishing Information
- Journal Title
- Journal of Radioanalytical and Nuclear Chemistry
- Journal Volume
- 255
- Journal Issue
- 2
- Journal Page Range
- p. 287-290
- ISSN
- 0236-5731
- CODEN
- JRNCDM
Conference
- Title
- Asia-Pacific Symposium on Radiochemistry. Part 2
- Dates
- 30 Oct - 1 Nov 2001
- Place
- Fukuoka (Japan)
INIS
- Country of Publication
- Hungary
- Country of Input or Organization
- Hungary
- INIS RN
- 34034489
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Resource subtype / Literary indicator
- Conference
- Descriptors DEI
- CONFIGURATION INTERACTION; ELECTRON TRANSFER; ELECTRONIC STRUCTURE; FERROCENE; IRON; IRON 57; MOESSBAUER EFFECT; MOLECULAR ORBITAL METHOD; VOLTAMETRY
- Descriptors DEC
- CALCULATION METHODS; COMPLEXES; DIENES; ELEMENTS; EVEN-ODD NUCLEI; HYDROCARBONS; INTERMEDIATE MASS NUCLEI; IRON COMPLEXES; IRON ISOTOPES; ISOTOPES; METALS; NUCLEI; ORGANIC COMPOUNDS; POLYENES; STABLE ISOTOPES; TRANSITION ELEMENT COMPLEXES; TRANSITION ELEMENTS
Optional Information
- Notes
- 6 refs.