Published February 15, 1987
| Version v1
Journal article
Structure of Cs6Zn5(MoO4)8
Creators
- 1. Technische Hochschule Aachen (Germany, F.R.). Lehrstuhl und Inst. fuer Kristallographie
Description
Mr=2403.83, cubic, Ianti 43d (unambiguously determined by X-ray diffraction), a=12.259(1) A, V=1842.32 A3, Z=2, Dm=4.48, Dx=4.3327 g cm-3, λ(CuKα) (for unit-cell dimensions)=1.5418, λ(AgKα) (for intensity measurements)=0.56081 A, μ(AgKα)=138.36 cm-1, F(000)=2144, T=293 K, final R=0.033 for 86 observed reflections. The Mo and Zn atoms form a three-dimensional tetrahedral framework [Mo-O distances 1.694(9)-1.758(9) A, Zn-O distances 1.975(8) A] and the Cs atoms are twelvefold coordinated by O atoms [Cs-O distances 3.273(8)-3.370(8) A], the coordination polyhedron being a distorted cubooctahedron. Refinement of the population factor resulted in 5/6 statistical occupation of the Zn position. (orig.)
Additional details
Publishing Information
- Journal Title
- Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
- Journal Volume
- 43
- Journal Issue
- 2
- Series
- Acta Crystallogr., Sect. C: Cryst. Struct. Commun.
- Journal Page Range
- 184-186
- ISSN
- 0108-2701
- CODEN
- ACSCE
INIS
- Country of Publication
- Denmark
- Country of Input or Organization
- Denmark
- INIS RN
- 18064467
- Subject category
- S36: MATERIALS SCIENCE;
- Resource subtype / Literary indicator
- Numerical Data
- Descriptors DEI
- CESIUM COMPOUNDS; CRYSTAL STRUCTURE; CUBIC LATTICES; EXPERIMENTAL DATA; INTERATOMIC DISTANCES; LATTICE PARAMETERS; MEDIUM TEMPERATURE; MOLYBDATES; X-RAY DIFFRACTION; ZINC COMPOUNDS
- Descriptors DEC
- ALKALI METAL COMPOUNDS; COHERENT SCATTERING; CRYSTAL LATTICES; DATA; DIFFRACTION; DISTANCE; INFORMATION; MOLYBDENUM COMPOUNDS; NUMERICAL DATA; OXYGEN COMPOUNDS; SCATTERING; TRANSITION ELEMENT COMPOUNDS