Synthesis and characterization of a layered chlorozincophosphate Zn(HPO4)Cl.[C4H10NO]
Creators
- 1. Laboratoire de chimie des Materiaux, Faculte des Sciences de Bizerte, 7021 Zarzouna (Tunisia)
Description
A chlorozincophosphate of the composition Zn(HPO4)Cl.[C4H10NO] has been synthesised under mild condition water medium in the presence of morpholine as organic template. Its unit cell is monoclinic P2 1/a with parameters a = 8.655(6) A, b = 9.302(5) A, c = 12.180(5) A, β = 101.10(4)o, Z = 4 and V = 962.1(9) A3. The structure was determinated by single crystal X-ray diffraction. The structure involves a network of ZnO3Cl and PO3(OH) tetrahedra forming macroanionic inorganic layers with four- and eight-membered rings. Charge balance is achieved by the protonated amine which is trapped in the interlayers space and interacts with the organic framework through hydrogen bonding. Solid state 31P and 13C MAS-NMR spectroscopies are in agreement with the X-ray structure
Additional details
Identifiers
- DOI
- 10.1016/j.materresbull.2006.05.028;
- PII
- S0025-5408(06)00237-6;
Publishing Information
- Journal Title
- Materials Research Bulletin
- Journal Volume
- 42
- Journal Issue
- 2
- Journal Page Range
- p. 288-298
- ISSN
- 0025-5408
- CODEN
- MRBUAC
INIS
- Country of Publication
- United States
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 39025350
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- AMINES; CARBON 13; CHEMICAL PREPARATION; MONOCLINIC LATTICES; MONOCRYSTALS; NUCLEAR MAGNETIC RESONANCE; SPECTROSCOPY; TRAPPING; X RADIATION; X-RAY DIFFRACTION
- Descriptors DEC
- CARBON ISOTOPES; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; CRYSTALS; DIFFRACTION; ELECTROMAGNETIC RADIATION; EVEN-ODD NUCLEI; IONIZING RADIATIONS; ISOTOPES; LIGHT NUCLEI; MAGNETIC RESONANCE; NUCLEI; ORGANIC COMPOUNDS; RADIATIONS; RESONANCE; SCATTERING; STABLE ISOTOPES; SYNTHESIS
Optional Information
- Copyright
- Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.