Published March 1985 | Version v1
Journal article

Synthesis and investigation of hydroxotetranitronitrosoruthenates (4) of bivalent metals

  • 1. Moskovskij Inst. Tonkoj Khimicheskoj Tekhnologii (USSR)

Description

Complexes of nitrosoruthenium M[RuNO(NO2)4xOH]xxH2O, where M2 - Mg, Sr, Ba, Zn, Pb, have been synthesized. Using the methods of IRS, roentgenography, thermography and electric conductivity, their properties are studied. It is found that perovskites BaRuO3 and SrRuO3 are the products of thermal decomposition of barium and strontium compounds, and decomposition of lead salt ends with the formation of double oxide of ruthenium and lead with pyrochlore structure. Effect of second sphere substituents on the properties of hydroxotetranitronitrosoruthenates(4) is discussed

Additional details

Additional titles

Original title (Russian)
Синтез и исследование гидроксотетранитронитрозорутенатов (4) двухвалентных металлов

Publishing Information

Journal Title
Zh. Neorg. Khim.
Journal Volume
30
Journal Issue
3
Series
Zh. Neorg. Khim.
Journal Page Range
704-710
ISSN
0044-457X

Optional Information

Notes
For English translation see the journal Russian Journal of Inorganic Chemistry (UK).