Published July 1, 2006
| Version v1
Journal article
Synthesis, structural characterization and thermochemical reactivity of tris(ethylenediamine)zinc tetracyanozincate, a precursor for nanoscale ZnO
- 1. Institute of Inorganic Chemistry, University of Duisburg-Essen, Universitaetsstrasse 5-7, D-45117 Essen (Germany)
Description
The binuclear complex tris(ethylenediamine)zinc tetracyanozincate was prepared and characterized by single-crystal X-ray structure analysis. It consists of distorted [Zn(en)3]2+ octahedra and [Zn(CN)4]2- tetrahedra. The thermolysis under air was studied by thermogravimetry, and the resulting product (ZnO) was characterized by X-ray diffraction and scanning electron microscopy, showing compact particles with a diameter of 100-300 nm
Additional details
Identifiers
- DOI
- 10.1016/j.tca.2006.01.002;
- PII
- S0040-6031(06)00005-0;
Publishing Information
- Journal Title
- Thermochimica Acta
- Journal Volume
- 446
- Journal Issue
- 1-2
- Journal Page Range
- p. 101-105
- ISSN
- 0040-6031
- CODEN
- THACAS
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 38084726
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CRYSTAL STRUCTURE; MONOCRYSTALS; NANOSTRUCTURES; REACTIVITY; SCANNING ELECTRON MICROSCOPY; SYNTHESIS; THERMAL GRAVIMETRIC ANALYSIS; X-RAY DIFFRACTION; ZINC COMPLEXES; ZINC OXIDES
- Descriptors DEC
- CHALCOGENIDES; CHEMICAL ANALYSIS; COHERENT SCATTERING; COMPLEXES; CRYSTALS; DIFFRACTION; ELECTRON MICROSCOPY; GRAVIMETRIC ANALYSIS; MICROSCOPY; OXIDES; OXYGEN COMPOUNDS; QUANTITATIVE CHEMICAL ANALYSIS; SCATTERING; THERMAL ANALYSIS; ZINC COMPOUNDS
Optional Information
- Copyright
- Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.