Published March 1980
| Version v1
Journal article
O17 NMR spectra of diphosphatopolyoxomolybdates
- 1. AN Kazakhskoj SSR, Alma-Ata. Inst. Khimicheskikh Nauk
- 2. AN SSSR, Novosibirsk. Inst. Kataliza
Description
Aqueous solutions of the salts Na6P2Mo18O62x52H2O(1), Na4H2P2Mo5O23x10H2O(2) and Na6P2Mo5O23x14H2O(3) with concentration 0.2(1), and 0.4(2)(3) mol/l have been studied using NMR method on the 17O and 31P nuclei. Chemical shifts of 17O and 31P NMR of heteropolyanions P2Mo5O236- and P2Mo18O626- are measured. It is shown that chemical shift of 17O NMR in polyoxomolybdate correlates with the distance to the nearest molybdenum atom
Additional details
Additional titles
- Original title (Russian)
- Спектры YaMR
Publishing Information
- Journal Title
- Izv. Akad. Nauk SSSR, Ser. Khim.
- Journal Issue
- no.3
- Series
- Izv. Akad. Nauk SSSR, Ser. Khim.
- ISSN
- 0002-3353
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- USSR
- INIS RN
- 12629006
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL SHIFT; HETEROPOLYANIONS; MOLYBDENUM COMPOUNDS; NMR SPECTRA; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS
- Descriptors DEC
- ANIONS; CHARGED PARTICLES; COMPLEXES; IONS; SPECTRA; TRANSITION ELEMENT COMPOUNDS
Optional Information
- Notes
- For English translation see the journal Bulletin of the Academy of Sciences USSR, Division of Chemical Science (USA).