Published September 15, 1999
| Version v1
Journal article
Bis[2-(2-ethoxyethyl)-N,N,N',N'-tetraethyl-malondiamide-O1,O3]tris(nitrato -O,O')-lanthanum(III)
- 1. CEA Centre d'Etudes de Saclay, 91 - Gif-sur-Yvette (France).
- 2. CEA Centre de Marcoule, 30 - Bagnols-sur-Ceze (France)
Description
2-(2-Ethoxyethyl)-N,N,N'N'-tetraethylmalondiamide (TEEEMA, C15H30N2O3) reacts with lanthanum(III) nitrate to give the title complex, [La(NO3)3(TEEEMA)2], in which the two carboxyl functions of each TEEEMA ligand are bonded to the metal ion together with three bidentate nitrate ions. This structure establishes that the ether O atom of the central chain of TEEEMA is not bonded to the metal ion, at least in the solid state. The coordination environment geometry is different from that of the lanthanum complex of N,N,N',N'-tetraethylmalondiamide (TEMA). (orig.)
Additional details
Publishing Information
- Journal Title
- Acta Crystallographica. Section C: Crystal Structure Communications
- Journal Volume
- 55
- Journal Issue
- 9
- Journal Page Range
- p. 1434-1436
- ISSN
- 0108-2701
- CODEN
- ACSCEE
INIS
- Country of Publication
- Denmark
- Country of Input or Organization
- Denmark
- INIS RN
- 31001740
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- AMIDES; LANTHANUM COMPLEXES; MALONIC ACID; MOLECULAR STRUCTURE; X-RAY DIFFRACTION
- Descriptors DEC
- CARBOXYLIC ACIDS; COHERENT SCATTERING; COMPLEXES; DICARBOXYLIC ACIDS; DIFFRACTION; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; RARE EARTH COMPLEXES; SCATTERING