Published September 15, 1999 | Version v1
Journal article

Bis[2-(2-ethoxyethyl)-N,N,N',N'-tetraethyl-malondiamide-O1,O3]tris(nitrato -O,O')-lanthanum(III)

  • 1. CEA Centre d'Etudes de Saclay, 91 - Gif-sur-Yvette (France).
  • 2. CEA Centre de Marcoule, 30 - Bagnols-sur-Ceze (France)

Description

2-(2-Ethoxyethyl)-N,N,N'N'-tetraethylmalondiamide (TEEEMA, C15H30N2O3) reacts with lanthanum(III) nitrate to give the title complex, [La(NO3)3(TEEEMA)2], in which the two carboxyl functions of each TEEEMA ligand are bonded to the metal ion together with three bidentate nitrate ions. This structure establishes that the ether O atom of the central chain of TEEEMA is not bonded to the metal ion, at least in the solid state. The coordination environment geometry is different from that of the lanthanum complex of N,N,N',N'-tetraethylmalondiamide (TEMA). (orig.)

Additional details

Publishing Information

Journal Title
Acta Crystallographica. Section C: Crystal Structure Communications
Journal Volume
55
Journal Issue
9
Journal Page Range
p. 1434-1436
ISSN
0108-2701
CODEN
ACSCEE