Investigation of neutral products of CO+ charge exchange on atoms and simple molecules
- 1. AN SSSR, Chernogolovka. Otdelenie Inst. Khimicheskoj Fiziki
Description
Using a device for studying neutral products of charge exchange relative cross sections, changes in translation energy, and excitation rate of CO-product molecules of CO+ change excharge on Kr, Ar, Xe, CO, NO, O2, N2O and C2H4 are determined. It is established, that in most cases no changes in translation energy of charge-exchange products take place, i.e. the processes studied proceed via the channels, corresponding to the random resonance condition. The results obtained can be explained in the framework of a presentation that the probability of this or that charge exchange channel is mainly determined by the Franck-Condon factor of the respective process of neutralization-ionization of reacting particles. For certain processes calculations of the absolute cross sections in the framework of the Rapp-Francis model with account of the Franck-Condon factors of the corresponding transitions are made, and the distributions of CO neutral molecules over electron-vibrational levels are evaluated. The calculation results agree well with the experiment
Additional details
Additional titles
- Original title (Russian)
- Исследование нейтральных продуктов перезарядки ионов CO
Publishing Information
- Journal Title
- Khim. Fiz.
- Journal Volume
- 4
- Journal Issue
- 6
- Series
- Khim. Fiz.
- Journal Page Range
- 828-837
- CODEN
- KHFID
INIS
- Country of Publication
- USSR
- Country of Input or Organization
- USSR
- INIS RN
- 17056060
- Subject category
- S74: ATOMIC AND MOLECULAR PHYSICS;
- Descriptors DEI
- ARGON; ATOMS; CARBON MONOXIDE; CHARGE EXCHANGE; CROSS SECTIONS; ENERGY DEPENDENCE; ETHYLENE; EV RANGE 10-100; FRANCK-CONDON PRINCIPLE; ION-ATOM COLLISIONS; ION-MOLECULE COLLISIONS; IONIZATION; IONS; KRYPTON; MOLECULES; NITROGEN OXIDES; OCCUPATION NUMBER; OXYGEN; RECOMBINATION; VIBRATIONAL STATES; XENON
- Descriptors DEC
- ALKENES; ATOM COLLISIONS; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHARGED PARTICLES; COLLISIONS; ELEMENTS; ENERGY LEVELS; ENERGY RANGE; EV RANGE; EXCITED STATES; HYDROCARBONS; ION COLLISIONS; MOLECULE COLLISIONS; NITROGEN COMPOUNDS; NONMETALS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; RARE GASES