Published 1990 | Version v1
Journal article Metadata-only

Synthesis and properties of lutetium complex with anthracene dianion

Creators

  • 1. Nauchno-Issledovatel'skij Fiziko-Khimicheskij Inst., Moscow (Russian Federation)

Description

The reaction of radicals anion and anthracene dianions with biscyclopentadienyllutetiumchliride in THF is studied. The produced compounds correspond to (C5H5)2Lu(C14H10)Na·C4H8O formula. It is highly soluble in THF ether and does not solve in hydrocarbons; it is sensitive to moisture and oxygen tracers. The interaction mechanism is considered. The results of reaction investigations agree with the data of the chemical analysis and confirm the conclusion on dianion nature of anthracene legand

Additional details

Additional titles

Original title (Russian)
Синтез и свойства комплекса лютеция с дианионом антрацена

Publishing Information

Journal Title
Doklady Akademii Nauk SSSR
Journal Volume
315
Journal Issue
6
Journal Page Range
p. 1393-1395.
ISSN
0002-3264
CODEN
DANKAS

INIS

Country of Publication
Russian Federation
Country of Input or Organization
Russian Federation
INIS RN
24031966
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ABSORPTION SPECTRA; ANIONS; ANTHRACENE; CHEMICAL PREPARATION; CHEMICAL PROPERTIES; CHEMICAL REACTION KINETICS; COORDINATION VALENCES; CYCLOPENTADIENE; LUTETIUM COMPLEXES; ORGANIC SOLVENTS; RADICALS; SOLUBILITY
Descriptors DEC
ALKENES; AROMATICS; CHARGED PARTICLES; COMPLEXES; CONDENSED AROMATICS; CYCLOALKENES; DIENES; HYDROCARBONS; IONS; KINETICS; NONAQUEOUS SOLVENTS; ORGANIC COMPOUNDS; POLYENES; RARE EARTH COMPLEXES; REACTION KINETICS; SOLVENTS; SPECTRA; SYNTHESIS; VALENCE