Published October 1991 | Version v1
Journal article Metadata-only

Study of reaction between halogens and phosphine using a perturbation method

Creators

  • 1. AN Kazakhskoj SSR, Alma-Ata (Kazakhstan). Inst. Organicheskogo Kataliza i Ehlektrokhimii

Description

Kinetic and activation parameters of reaction between halogens and phosphine at different pH are compared with stabilization energy calculated by the perturbation method. It is shown that Hal(OH2)+ and HalOH particles reacting with phosphine via O atom are responsible for the reaction. Reactivity of halogens decreases in the series: Hal2>HalOH; Cl2>Br2>I2

Additional details

Additional titles

Original title (Russian)
Исследование методом возмущений реакции галогенов с фосфином

Publishing Information

Journal Title
Zhurnal Neorganicheskoj Khimii
Journal Volume
36
Journal Issue
10
Series
Zh. Neorg. Khim.
Journal Page Range
2699-2703
ISSN
0044-457X
CODEN
ZNOKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
23041578
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
ACTIVATION ENERGY; AQUEOUS SOLUTIONS; CHEMICAL REACTION KINETICS; CHEMICAL REACTIONS; HYPOIODOUS ACID; IODINE; PH VALUE; PHOSPHINES; TEMPERATURE RANGE 0273-0400 K
Descriptors DEC
DISPERSIONS; ELEMENTS; ENERGY; HALOGEN COMPOUNDS; HALOGENS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; IODINE COMPOUNDS; KINETICS; MIXTURES; NONMETALS; OXYGEN COMPOUNDS; PHOSPHORUS COMPOUNDS; REACTION KINETICS; SOLUTIONS; TEMPERATURE RANGE