Published December 2005 | Version v1
Journal article

Measurement and modeling of mean activity coefficients of NaBr and amino acid in (sodium bromide + potassium phosphate + glycine + water) system at T (298.15 and 308.15) K

  • 1. Department of Chemical Engineering, Amirkabir University of Technology, Tehran (Iran, Islamic Republic of)

Description

Electrochemical measurements are done on (water + NaBr + K3PO4 + glycine) mixtures at T (298.15 and 308.15) K by using (Na+ glass) and (Br- solid-state) ion selective electrodes. The mean ionic activity coefficients of NaBr are determined at five NaBr molalities (0.1, 0.3, 0.5, 0.7, and 1) in the above mixtures. The activity coefficients of glycine are evaluated from mean ionic activity coefficients of sodium bromide. The ratio of mean ionic activity coefficient of NaBr in the (water + NaBr + K3PO4 + glycine) mixtures to the mean ionic activity coefficients of NaBr at the same molalities in the (H2O + NaBr) mixtures are correlated by using a new expression

Additional details

Identifiers

DOI
10.1016/j.jct.2005.03.018;
PII
S0021-9614(05)00068-6;

Publishing Information

Journal Title
Journal of Chemical Thermodynamics
Journal Volume
37
Journal Issue
12
Journal Page Range
p. 1305-1311
ISSN
0021-9614
CODEN
JCTDAF

Optional Information

Copyright
Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.