Published December 2005
| Version v1
Journal article
Measurement and modeling of mean activity coefficients of NaBr and amino acid in (sodium bromide + potassium phosphate + glycine + water) system at T (298.15 and 308.15) K
Creators
- 1. Department of Chemical Engineering, Amirkabir University of Technology, Tehran (Iran, Islamic Republic of)
Description
Electrochemical measurements are done on (water + NaBr + K3PO4 + glycine) mixtures at T (298.15 and 308.15) K by using (Na+ glass) and (Br- solid-state) ion selective electrodes. The mean ionic activity coefficients of NaBr are determined at five NaBr molalities (0.1, 0.3, 0.5, 0.7, and 1) in the above mixtures. The activity coefficients of glycine are evaluated from mean ionic activity coefficients of sodium bromide. The ratio of mean ionic activity coefficient of NaBr in the (water + NaBr + K3PO4 + glycine) mixtures to the mean ionic activity coefficients of NaBr at the same molalities in the (H2O + NaBr) mixtures are correlated by using a new expression
Additional details
Identifiers
- DOI
- 10.1016/j.jct.2005.03.018;
- PII
- S0021-9614(05)00068-6;
Publishing Information
- Journal Title
- Journal of Chemical Thermodynamics
- Journal Volume
- 37
- Journal Issue
- 12
- Journal Page Range
- p. 1305-1311
- ISSN
- 0021-9614
- CODEN
- JCTDAF
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 37024599
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- BROMINE IONS; ELECTROLYTES; GLASS; GLYCINE; ION-SELECTIVE ELECTRODES; POTASSIUM PHOSPHATES; REACTION KINETICS; SIMULATION; SODIUM BROMIDES; SODIUM IONS; SOLIDS; SOLUTIONS; TEMPERATURE RANGE 0400-1000 K; THERMODYNAMIC ACTIVITY; WATER
- Descriptors DEC
- ALKALI METAL COMPOUNDS; AMINO ACIDS; BROMIDES; BROMINE COMPOUNDS; CARBOXYLIC ACIDS; CHARGED PARTICLES; DISPERSIONS; ELECTRODES; HALIDES; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; IONS; KINETICS; MIXTURES; ORGANIC ACIDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PHOSPHATES; PHOSPHORUS COMPOUNDS; POTASSIUM COMPOUNDS; SODIUM COMPOUNDS; TEMPERATURE RANGE
Optional Information
- Copyright
- Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.