Published July 15, 2005
| Version v1
Journal article
Zero-field splitting and g-factor studies for 3d5 ions in tetragonal and trigonal symmetry
Creators
- 1. Department of Applied Physics, University of Electronic Science and Technology of China, Chengdu 610054 (China)
- 2. Department of Applied Physics, University of Electronic Science and Technology of China, Chengdu 610054 (China) and International Center for Material Physics, Chinese Academy of Sciences, Shengyang 110015 (China)
- 3. Institute of Solid State Physics, Sichuan Normal University, Chengdu, 610066 (China)
Description
In this paper, the rigorous analytical expressions for the zero field splittings D, a, F and g-factors of a 3d5 ion in tetragonal and trigonal crystal fields are derived. In the derivations, the energy levels equivalence between microscopic Zeeman interaction and phenomenological spin-Hamiltonian was used. The deduced expressions do not depend on any interaction model and are universal expressions. As some examples, we studied the specific examples of MnCO3,Rb2CdF4:Mn2+ and KZnF3:Mn2+. Good agreement between calculation and experiments shows that the formulas are reasonable
Additional details
Identifiers
- DOI
- 10.1016/j.physb.2005.03.044;
- PII
- S0921-4526(05)00672-1;
Publishing Information
- Journal Title
- Physica. B, Condensed Matter
- Journal Volume
- 364
- Journal Issue
- 1-4
- Journal Page Range
- p. 122-129
- ISSN
- 0921-4526
- CODEN
- PHYBE3
INIS
- Country of Publication
- Netherlands
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 37068202
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- CADMIUM FLUORIDES; COBALT OXIDES; CRYSTAL FIELD; ENERGY LEVELS; HAMILTONIANS; LANDE FACTOR; MANGANESE COMPOUNDS; MANGANESE IONS; POTASSIUM COMPOUNDS; RUBIDIUM COMPOUNDS; SPIN; SYMMETRY; ZEEMAN EFFECT; ZINC FLUORIDES
- Descriptors DEC
- ALKALI METAL COMPOUNDS; ANGULAR MOMENTUM; CADMIUM COMPOUNDS; CADMIUM HALIDES; CHALCOGENIDES; CHARGED PARTICLES; COBALT COMPOUNDS; DIMENSIONLESS NUMBERS; FLUORIDES; FLUORINE COMPOUNDS; HALIDES; HALOGEN COMPOUNDS; IONS; MATHEMATICAL OPERATORS; OXIDES; OXYGEN COMPOUNDS; PARTICLE PROPERTIES; QUANTUM OPERATORS; TRANSITION ELEMENT COMPOUNDS; ZINC COMPOUNDS; ZINC HALIDES
Optional Information
- Copyright
- Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.