Published 1991 | Version v1
Journal article

Transport of actinides and Tc through a bentonite backfill containing small quantities of iron or copper

  • 1. Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Nuclear Chemistry

Description

In the Swedish concept for final disposal of high-level radioactive waste, compacted bentonite has been proposed as a suitable backfill. The apparent diffusivity (Da) of the actinides U, Pu, Np and the fission product Tc in compacted bentonite mixed with 1% Fe(0), Fe(II), Cu(0) or Cu(II) has been measured in an inert nitrogen atmosphere. The results indicate, especially in the case of Fe(0) or Fe(II), reduction from the higher oxidation state Np(V), U(VI) and Tc(VII) probably to Np(IV), U(IV) and Tc(IV). (orig.)

Additional details

Publishing Information

Journal Title
Radiochimica Acta
Journal Volume
52/53
Journal Issue
pt.1
Series
Radiochim. Acta.
Journal Page Range
283-286
ISSN
0033-8230
CODEN
RAACA

Conference

Title
2. international conference on chemistry and migration behavior of actinides and fission products in the geosphere (Migration '89).
Dates
6-10 Nov 1989.
Place
Monterey, CA (USA).