Published 1992 | Version v1
Journal article

The molecular dynamic of N H4 H2 P O4 by neutron spectroscopy

  • 1. Institute of Physics and Nuclear Engineering, Bucharest, P.O.Box MG-6 (Romania)
  • 2. Joint Institute of Nuclear Research, Dubna, Moscow Region, (Russian Federation)

Description

The generalized one-phonon density of states on ADP (N H4 H2 P O4) from inelastic neutron scattering spectra at 90, 103, 133, 155, 196, 248, 298 K was determined. The energy transitions can be divided in three parts. The first part is connected with the normal modes of the lattice. The second part displays the peak due to the hindered rotations of the ammonium ion. THe last part of the spectrum is connected with intramolecular vibrations. The dynamical aspects of the paraelectric-antiferroelectric phase transition at 148 K are discussed. (Author)

Additional details

Publishing Information

Journal Title
Romanian Journal of Physics
Journal Volume
37
Journal Issue
4
Journal Page Range
p. 425-435.
ISSN
1221-146X
CODEN
RJPHEC