Published January 31, 2005
| Version v1
Journal article
Space-time thermodynamics of the glass transition
Description
We consider the probability distribution for the fluctuations in the dynamical action of glass forming materials. We argue that the so-called glass transition is a manifestation of low action tails in these distributions where the entropy of trajectory space is sub-extensive in time. These low action tails are a consequence of dynamic heterogeneity and an indication of phase coexistence in trajectory space. The glass transition, where the system falls out of equilibrium, is then an order-disorder phenomenon in space-time occurring at a temperature Tg which is a weak function of measurement time. We illustrate our perspective ideas with facilitated lattice models, and note how these ideas apply more generally
Availability note (English)
Available from OSTI as DE00918555; PURL: https://www.osti.gov/servlets/purl/918555-iV91fp/Additional details
Identifiers
Publishing Information
- Journal Title
- Proceedings of the National Academy of Sciences of the United States of America
- Journal Volume
- 102
- Journal Issue
- 31
- Journal Page Range
- vp.
- ISSN
- 0027-8424
- CODEN
- PNASA6
INIS
- Country of Publication
- United States
- Country of Input or Organization
- United States
- INIS RN
- 39104247
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- DISTRIBUTION; ENTROPY; FLUCTUATIONS; GLASS; PROBABILITY; SPACE-TIME; THERMODYNAMICS
- Descriptors DEC
- PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES; VARIATIONS
Optional Information
- Contract/Grant/Project number
- NSF:CHE-0078458; AC02-05CH11231
- Notes
- Journal Publication Date: 08/02/2005
- Funding organization
- US Department of Energy (United States); National Science Foundation GrantCHE-0078458 (United States)
- Secondary number(s)
- LBNL--56975