Published January 31, 2005 | Version v1
Journal article

Space-time thermodynamics of the glass transition

Description

We consider the probability distribution for the fluctuations in the dynamical action of glass forming materials. We argue that the so-called glass transition is a manifestation of low action tails in these distributions where the entropy of trajectory space is sub-extensive in time. These low action tails are a consequence of dynamic heterogeneity and an indication of phase coexistence in trajectory space. The glass transition, where the system falls out of equilibrium, is then an order-disorder phenomenon in space-time occurring at a temperature Tg which is a weak function of measurement time. We illustrate our perspective ideas with facilitated lattice models, and note how these ideas apply more generally

Availability note (English)

Available from OSTI as DE00918555; PURL: https://www.osti.gov/servlets/purl/918555-iV91fp/

Additional details

Publishing Information

Journal Title
Proceedings of the National Academy of Sciences of the United States of America
Journal Volume
102
Journal Issue
31
Journal Page Range
vp.
ISSN
0027-8424
CODEN
PNASA6

INIS

Country of Publication
United States
Country of Input or Organization
United States
INIS RN
39104247
Subject category
S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
Descriptors DEI
DISTRIBUTION; ENTROPY; FLUCTUATIONS; GLASS; PROBABILITY; SPACE-TIME; THERMODYNAMICS
Descriptors DEC
PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES; VARIATIONS

Optional Information

Contract/Grant/Project number
NSF:CHE-0078458; AC02-05CH11231
Notes
Journal Publication Date: 08/02/2005
Funding organization
US Department of Energy (United States); National Science Foundation GrantCHE-0078458 (United States)
Secondary number(s)
LBNL--56975