Published September 2018 | Version v1
Journal article Metadata-only

Conducting properties of nanocomposite polymer electrolytes based on polyethylene glycol diacrylate and SiO2 nanoparticles at the interface with a lithium electrode

Creators

  • 1. Russian Academy of Sciences, Institute of Problems of Chemical Physics (Russian Federation)

Description

Nanocomposite polymer electrolytes based on polyethylene glycol diacrylate and 1 M LiBF4 solution in γ-butyrolactone with addition of SiO2 nanoparticles were synthesized and studied. Resistance measurement at the Li/electrolyte and Li/nanocomposite electrolyte interface by the time-resolved electrochemical impedance showed its significant decrease in the presence of SiO2 nanoparticles. Charge-discharge cycling of prototypes of Li/LiFePO4 batteries for 50 cycles also showed the advantage of using nanocomposite polymer electrolytes over electrolytes without SiO2 additives.

Additional details

Identifiers

DOI
10.1007/s11172-018-2272-7;

Publishing Information

Journal Title
Russian Chemical Bulletin
Journal Volume
67
Journal Issue
9
Journal Page Range
p. 1648-1654
ISSN
1066-5285
CODEN
RCBUEY

INIS

Country of Publication
United States
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
51025099
Subject category
S77: NANOSCIENCE AND NANOTECHNOLOGY;
Descriptors DEI
ACRYLATES; ELECTROCHEMISTRY; ELECTROLYTES; IMPEDANCE; IONIC CONDUCTIVITY; LITHIUM; NANOCOMPOSITES; NANOPARTICLES; POLYETHYLENE GLYCOLS; SILICON OXIDES; TIME RESOLUTION
Descriptors DEC
ALCOHOLS; ALKALI METALS; CARBOXYLIC ACID SALTS; CHALCOGENIDES; CHEMISTRY; ELECTRIC CONDUCTIVITY; ELECTRICAL PROPERTIES; ELEMENTS; ETHYLENE GLYCOLS; GLYCOLS; HYDROXY COMPOUNDS; MATERIALS; METALS; NANOMATERIALS; ORGANIC COMPOUNDS; ORGANIC POLYMERS; OXIDES; OXYGEN COMPOUNDS; PARTICLES; PHYSICAL PROPERTIES; POLYMERS; RESOLUTION; SILICON COMPOUNDS; TIMING PROPERTIES

Optional Information

Copyright
Copyright (c) 2018 Springer Science+Business Media, LLC, part of Springer Nature