Published 1993
| Version v1
Journal article
Reactions of 2,3-dimethylene-1,4-bis(dipropylboryl)butane with carbonyl compounds
- 1. AN SSSR, Moscow (Russian Federation). Inst. Organicheskoj Khimii
Description
2,3-Dimethylene-1,4-bis(dipropylboryl)butane (1), prepared by borylation of 2,3-dimethylbutadienyl dipotassium, reacts with ketones to form symmetrical diene diols in the yield of 46-73 %. [4+2]-Cycloaddition reactions of diborane 1 to 1,2-dicarbonyl compounds proceed highly stereospecifically, affording only cis-isomers of 4,5-dimethylenecyclohexane-1,2-diols
Additional details
Additional titles
- Original title (Russian)
- Реакции 2,3-диметилен-1,4-бис(дипропилборил)бутана с карбонильными соединениями
Publishing Information
- Journal Title
- Izvestiya Akademii Nauk - Rossijskaya Akademiya Nauk. Seriya Khimicheskaya
- Journal Issue
- no.1
- Journal Page Range
- p. 155-159.
- ISSN
- 0002-3353
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- Russian Federation
- INIS RN
- 25001844
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- CHEMICAL PREPARATION; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; ISOMERS; KETONES; MOLECULAR STRUCTURE; ORGANIC BORON COMPOUNDS
- Descriptors DEC
- KINETICS; ORGANIC COMPOUNDS; REACTION KINETICS; SYNTHESIS; YIELDS