Published November 5, 2012 | Version v1
Journal article

Time-resolved XUV-induced isomerization and H3 formation in C2H4 cation

  • 1. Max-Planck-Institut für Kernphysik, 69117 Heidelberg (Germany)
  • 2. Max-Planck Advanced Study Group, 22607 Hamburg (Germany)
  • 3. Max-Planck-Institut für Quantenoptik, 85748 Garching (Germany)
  • 4. LBNL, Lawrence Berkeley National Laboratory, 94720 California (United States)
  • 5. Institute of Multidisciplinary Research for Advanced Materials, Tohoku University (Japan)
  • 6. DESY, 22607 Hamburg (Germany)

Description

Using a split-mirror setup attached to a Reaction Microscope at the Free electron LASer in Hamburg (FLASH) we traced as function of time the migration of a hydrogen atom in C2H4+ from one end of the molecule to the other by coincident CH+ + CH3+ fragment detection. In addition, the observed H3++C2H+ channel provides for the first time evidence for an isomerization-induced formation mechanism of H3+ molecules.

Availability note (English)

Available from http://dx.doi.org/10.1088/1742-6596/388/3/032014

Additional details

Publishing Information

Journal Title
Journal of Physics. Conference Series (Online)
Journal Volume
388
Journal Issue
3
Journal Page Range
[1 p.]
ISSN
1742-6596

Conference

Title
27. international conference on photonic, electronic and atomic collisions
Acronym
ICPEAC 2011
Dates
27 Jul - 2 Aug 2011
Place
Belfast, Northern Ireland (United Kingdom)