Published August 2018 | Version v1
Journal article

Universal aging characteristics of macroscopically and microscopically dissimilar metallic glasses

  • 1. Department of Physics, City University of Hong Kong, Kowloon Tong, Hong Kong (China)
  • 2. Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)
  • 3. Research & Utilization Division, Japan Synchrotron Radiation Research Institute, Hyogo 679-5198 (Japan)

Description

Supercooled liquids and glasses, due to their intrinsically unstable nature, are known to relax continuously until an equilibrium state is reached. By exploring atomic relaxation, aging and microscopic structure of chemically similar but physically dissimilar metallic glasses, we find that neither the relaxation time nor aging correlate with the free volume or density of the glasses. Furthermore, atomic relaxation time in these metallic glasses does not depend on the microscopic structure of the systems. The activation energy for the diffusion process indicates a completely different microscopic mechanism governing the atomic transport process. Nevertheless, the age-dependent relaxation time surprisingly exhibits a universal time-waiting time-temperature superposition. Our results provide a convincing proof of the universality in the aging of out-of-equilibrium materials.

Availability note (English)

Available from http://dx.doi.org/10.1016/j.actamat.2018.05.059

Additional details

Identifiers

DOI
10.1016/j.actamat.2018.05.059;
PII
S1359645418304269;

Publishing Information

Journal Title
Acta Materialia
Journal Volume
155
Journal Page Range
p. 35-42
ISSN
1359-6454
CODEN
ACMAFD

INIS

Country of Publication
United Kingdom
Country of Input or Organization
International Atomic Energy Agency (IAEA)
INIS RN
49095658
Subject category
S36: MATERIALS SCIENCE;
Descriptors DEI
ACTIVATION ENERGY; AGE DEPENDENCE; AGING; ATOM TRANSPORT; GLASS; METALLIC GLASSES; MOLECULAR DYNAMICS METHOD; MONTE CARLO METHOD; RELAXATION TIME; X RADIATION
Descriptors DEC
CALCULATION METHODS; ELECTROMAGNETIC RADIATION; ENERGY; IONIZING RADIATIONS; NEUTRAL-PARTICLE TRANSPORT; RADIATION TRANSPORT; RADIATIONS

Optional Information

Copyright
Copyright (c) 2017 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.