Universal aging characteristics of macroscopically and microscopically dissimilar metallic glasses
Creators
- 1. Department of Physics, City University of Hong Kong, Kowloon Tong, Hong Kong (China)
- 2. Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)
- 3. Research & Utilization Division, Japan Synchrotron Radiation Research Institute, Hyogo 679-5198 (Japan)
Description
Supercooled liquids and glasses, due to their intrinsically unstable nature, are known to relax continuously until an equilibrium state is reached. By exploring atomic relaxation, aging and microscopic structure of chemically similar but physically dissimilar metallic glasses, we find that neither the relaxation time nor aging correlate with the free volume or density of the glasses. Furthermore, atomic relaxation time in these metallic glasses does not depend on the microscopic structure of the systems. The activation energy for the diffusion process indicates a completely different microscopic mechanism governing the atomic transport process. Nevertheless, the age-dependent relaxation time surprisingly exhibits a universal time-waiting time-temperature superposition. Our results provide a convincing proof of the universality in the aging of out-of-equilibrium materials.
Availability note (English)
Available from http://dx.doi.org/10.1016/j.actamat.2018.05.059Additional details
Identifiers
- DOI
- 10.1016/j.actamat.2018.05.059;
- PII
- S1359645418304269;
Publishing Information
- Journal Title
- Acta Materialia
- Journal Volume
- 155
- Journal Page Range
- p. 35-42
- ISSN
- 1359-6454
- CODEN
- ACMAFD
INIS
- Country of Publication
- United Kingdom
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 49095658
- Subject category
- S36: MATERIALS SCIENCE;
- Descriptors DEI
- ACTIVATION ENERGY; AGE DEPENDENCE; AGING; ATOM TRANSPORT; GLASS; METALLIC GLASSES; MOLECULAR DYNAMICS METHOD; MONTE CARLO METHOD; RELAXATION TIME; X RADIATION
- Descriptors DEC
- CALCULATION METHODS; ELECTROMAGNETIC RADIATION; ENERGY; IONIZING RADIATIONS; NEUTRAL-PARTICLE TRANSPORT; RADIATION TRANSPORT; RADIATIONS
Optional Information
- Copyright
- Copyright (c) 2017 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.