Published 1989 | Version v1
Journal article Metadata-only

Kinetics of reactions of Np and Pu ions with hydrazine derivatives

Creators

Description

Kinetics of Np(6) reduction by allyl-, formyl- and acetylhydrazine in HNO3 and HClO2 aqueous solutions was studied. Kinetic equations of studied reactions are suggested, and their mechanism is discussed. Values of activation energy, enthalpy, entropy and free activation energy for these reactions were calculated. Correlation of rate constants with induction effects of radicals-substituents in hydrazine molecule is noted

Additional details

Additional titles

Subtitle (English)
5. Np(6) reduction by allyl-, formyl- and acetylhydrazine
Original title (Russian)
Кинетика реакций ионов Нп и Пу с производными гидразина
Original subtitle (Russian)
5. Vosstanovlenie Np(6) allil-, formil- i atsetilgidrazinom.

Publishing Information

Journal Title
Radiokhimiya
Journal Volume
31
Journal Issue
2
Series
Radiokhimiya.
Journal Page Range
34-40
ISSN
0033-8311
CODEN
RADKA

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
21062297
Subject category
S38: RADIATION CHEMISTRY, RADIOCHEMISTRY AND NUCLEAR CHEMISTRY;
Descriptors DEI
ACTIVATION ENERGY; AQUEOUS SOLUTIONS; CHEMICAL REACTION KINETICS; ENTHALPY; ENTROPY; FREE ENTHALPY; MEDIUM TEMPERATURE; NEPTUNYL COMPOUNDS; NITRIC ACID; ORGANIC NITROGEN COMPOUNDS; PERCHLORIC ACID; REDUCTION
Descriptors DEC
ACTINIDE COMPOUNDS; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; DISPERSIONS; ENERGY; HALOGEN COMPOUNDS; HOMOGENEOUS MIXTURES; HYDROGEN COMPOUNDS; INORGANIC ACIDS; INORGANIC COMPOUNDS; KINETICS; MIXTURES; NEPTUNIUM COMPOUNDS; NITROGEN COMPOUNDS; ORGANIC COMPOUNDS; OXYGEN COMPOUNDS; PHYSICAL PROPERTIES; REACTION KINETICS; SOLUTIONS; THERMODYNAMIC PROPERTIES; TRANSURANIUM COMPOUNDS