A study of optical band gap in GeSxSe_1-x (x = 0, 0.5, 1) single crystals grown using chemical vapour transport technique

Two-dimensional transition metal chalcogenides like GeSe, GeS and SnSe are widely used in a variety of electrical and optoelectrical applications. Alloying becomes the most important tool to alter the structural, optical and electrical properties of the material. Here, efforts have been applied to grow the crystals of GeS_xSe_1-x (x = 0,0.5,1) using iodine (I2) as a transporting agent by the chemical vapour transport technique. The elemental confirmation of grown crystals was done by the energy-dispersive analysis of X-rays. The lattice parameters were obtained from powder X-ray diffraction patterns of all the grown compounds. For the optical study of grown compounds, UV-Vis spectroscopy was performed in the wavelength range of 700-1450 nm. The optical absorption process was studied in detail using the direct and the indirect transitions from two- and three-dimensional models. Moreover, band-gap modification by incorporating sulphur in different concentrations is studied. It is found that the band gap increases with increasing sulphur content in germanium selenide crystals. (author)