Published November 25, 2020
| Version v1
Journal article
Structure of Organic Compound (E)-3-((S)1-Phenylethylamine)methylene R (+) Camphor
- 1. Departamento de Química, Facultad de Ciencias Naturales, Universidad Metropolitana de Ciencias de la Educación (Chile)
- 2. Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad de Concepción, Edmundo Larenas 234 (Chile)
- 3. INQUIMAE, CONICET and Departamento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón II, Ciudad Universitaria, Núñez (C1428EHA) (Argentina)
- 4. Gerencia de Investigación y Aplicaciones, Centro Atómico Constituyentes, Comisión Nacional de Energía Atómica (Argentina)
- 5. Facultad de Ciencias Básicas, Universidad Santo Tomás, Limonares 190 (Chile)
Description
The synthesis and crystal structure of (E)-3-((S)-1-phenylethylamine)methylene R-(+) camphor are discussed. The 1H NMR spectrum in a chloroform solution indicates the existence of a mixture of two tautomers, the main tautomer corresponds to the E-isomer. On the other hand, in the solid state, the crystal structure solved by X-ray diffraction shows only the occurrence of this latter form. Crystal data: monoclinic (P21), a = 11.019(4) Å, b = 6.782(2) Å, c = 11.186(4) Å, β = 101.843(4)°.
Additional details
Identifiers
Publishing Information
- Journal Title
- Crystallography Reports
- Journal Volume
- 65
- Journal Issue
- 7
- Journal Page Range
- p. 1150-1155
- ISSN
- 1063-7745
- CODEN
- CYSTE3
INIS
- Country of Publication
- Russian Federation
- Country of Input or Organization
- International Atomic Energy Agency (IAEA)
- INIS RN
- 55060695
- Subject category
- S75: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY;
- Descriptors DEI
- BOND ANGLE; BOND LENGTHS; CAMPHOR; CHEMICAL PREPARATION; CHEMICAL SHIFT; CHLOROFORM; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; LATTICE PARAMETERS; MOLECULAR STRUCTURE; MONOCLINIC LATTICES; NMR SPECTRA; NUCLEAR MAGNETIC RESONANCE; SOLUTIONS; SPACE GROUPS; X-RAY DIFFRACTION
- Descriptors DEC
- CHLORINATED ALIPHATIC HYDROCARBONS; COHERENT SCATTERING; CRYSTAL LATTICES; CRYSTAL STRUCTURE; DIFFRACTION; DIMENSIONS; DISPERSIONS; HALOGENATED ALIPHATIC HYDROCARBONS; HOMOGENEOUS MIXTURES; KETONES; LENGTH; MAGNETIC RESONANCE; MIXTURES; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; RESONANCE; SCATTERING; SPECTRA; SYMMETRY GROUPS; SYNTHESIS; TERPENES; THREE-DIMENSIONAL LATTICES
Optional Information
- Copyright
- Copyright (c) 2020 © Pleiades Publishing, Inc. 2020. ISSN 1063-7745, Crystallography Reports, 2020, Vol. 65, No. 7, pp. 1150#En Dash#1155. © Pleiades Publishing, Inc., 2020.