Published May 1982 | Version v1
Journal article Metadata-only

Magnetic isotope effect and oxygen enrichment by 17O isotope in chain oxidation reactions. Communication 1. Theory

Creators

  • 1. AN SSSR, Moscow. Inst. Khimicheskoj Fiziki

Description

The theory of magnetic isotope effect and enrichment of molecular oxygen by 17O isotope in chain oxidation reactions of organic compounds is presented. Recombination probabilities of perioxide radicals differing by isotope composition by oxygen are calculated; the magnetic isotope effect and its dependence on diffusion and viscosity coefficients are determined. Some geochemical and space-chemical consequences of the magnetic isotope effect are discussed

Additional details

Additional titles

Original title (Russian)
Магнитный изотопный эффект и обогащение кислорода изотопом

Publishing Information

Journal Title
Izv. Akad. Nauk SSSR, Ser. Khim.
Journal Issue
no.5
Series
Izv. Akad. Nauk SSSR, Ser. Khim.
ISSN
0002-3353

INIS

Country of Publication
Russian Federation
Country of Input or Organization
USSR
INIS RN
14740746
Subject category
S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
Descriptors DEI
CHAIN REACTIONS; DIFFUSION; EQUATIONS; ISOTOPE EFFECTS; ISOTOPE SEPARATION; NUCLEAR MAGNETIC MOMENTS; ORGANIC COMPOUNDS; OXIDATION; OXYGEN; OXYGEN 17; PEROXY RADICALS; PROBABILITY; VISCOSITY
Descriptors DEC
CHEMICAL REACTIONS; ELEMENTS; EVEN-ODD NUCLEI; ISOTOPES; LIGHT NUCLEI; MAGNETIC MOMENTS; NONMETALS; NUCLEAR PROPERTIES; NUCLEI; OXYGEN ISOTOPES; RADICALS; SEPARATION PROCESSES; STABLE ISOTOPES

Optional Information

Notes
For English translation see the journal Bulletin of the Academy of Sciences USSR, Division of Chemical Science (USA).