Published August 1991
| Version v1
Journal article
Synthesis and spectral studies of some azinate complexes with titanium(IV) and zirconium(IV)
Creators
- 1. Mosul Univ. (Iraq). College of Education
- 2. Al-Mustansiriya Univ. (Iraq). College of Science
Description
Complexes of Tisup(IV) and Zrsup(IV) with furfuraldazine, 2-thiophenaldazine and 2-pyridinaldazine have been synthesised and characterised on the basis of elemental analysis, molar conductance and ir and uv spectral data. Molar conductance values suggest that the complexes are 1:4 electrolytes in 10-3 M dimethyl formamide (DMF) solutions. The ir spectra reflect the involvement of only three coordination sites of the azine ligands in bonding to metal ions. The formula [ML2]X4 (where L = azine ligand, X Cl- or NO3- ion; M=metal ion) has been proposed for the complexes. (author). 11 refs., 2 tabs
Additional details
Publishing Information
- Journal Title
- Journal of the Indian Chemical Society
- Journal Volume
- 68
- Journal Issue
- 8
- Journal Page Range
- p. 433-434.
- ISSN
- 0019-4522
- CODEN
- JICSAH
INIS
- Country of Publication
- India
- Country of Input or Organization
- India
- INIS RN
- 25035701
- Subject category
- S37: INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY;
- Descriptors DEI
- ABSORPTION SPECTRA; AZINES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; COLOR; ELECTRIC CONDUCTIVITY; INFRARED SPECTRA; LIGANDS; MELTING POINTS; STRUCTURAL CHEMICAL ANALYSIS; ZIRCONIUM COMPLEXES
- Descriptors DEC
- COMPLEXES; ELECTRICAL PROPERTIES; HETEROCYCLIC COMPOUNDS; OPTICAL PROPERTIES; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANOLEPTIC PROPERTIES; PHYSICAL PROPERTIES; SPECTRA; SYNTHESIS; THERMODYNAMIC PROPERTIES; TRANSITION ELEMENT COMPLEXES; TRANSITION TEMPERATURE